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The Schrödinger equation

Statement

iℏ ∂tψ=H^ψ=−ℏ22m∇2ψ+Vψi\hbar\,\partial_t\psi = \hat{H}\psi = -\dfrac{\hbar^2}{2m}\nabla^2\psi + V\psi — the fundamental equation describing the time evolution of the quantum wavefunction ψ\psi.

Why is it true?

Plays the role of Newton's second law but for the quantum world: knowing ψ\psi at one instant and the potential VV, the equation tells you what ψ\psi will be at a later instant.

A wave packet propagating and dispersing under iħ∂ψ/∂t = Ĥψ: at wells and barriers it partly reflects and tunnels; |ψ|² gives detection probability.

Stated by

Topics that use this theorem

Related theorems

Step-by-step proofs

No step-by-step proof yet for this theorem.

References

  1. Erwin Schrödinger (1926). Quantisierung als Eigenwertproblem