Physic Labs

Condensed matter physics

Free-electron gas and the Fermi level

Explore the free-electron gas: view the spherical Fermi surface in k-space, check kF=(3π2n)1/3k_F = (3\pi^2 n)^{1/3} and EF∝n2/3E_F \propto n^{2/3}, and watch the thermal smearing ∼kBT\sim k_BT of the Fermi–Dirac distribution around EFE_F.

Advanced

Equipment

  • 3D Fermi sphere in k-space with occupied states
  • “Temperature” slider (5–180 simulation units)
  • “Density / frequency” and “Number of states” sliders
  • Occupation-distribution plot versus ε/E_F and the “Pause” button

Procedure

  1. Change the density and gauge the Fermi radius

    Raise “Density / frequency”: the Fermi sphere inflates in k-space as more states get occupied. Compare its radius with kF=(3π2n)1/3k_F = (3\pi^2 n)^{1/3} and the edge energy EF=ℏ2kF2/2m∝n2/3E_F = \hbar^2k_F^2/2m \propto n^{2/3} — press “Pause” to read the occupied-state count.

  2. Sweep the temperature and watch the Fermi edge blur

    At low T the occupation is nearly a step: all states ε < E_F full, ε > E_F empty. Raise “Temperature”: only a band ∼kBT\sim k_BT wide around EFE_F blurs — electrons deep inside the sphere cannot be excited since nearby states are occupied (Pauli principle).

  3. Change the state count and draw consequences

    Sweep “Number of states” to see the density of states change, then combine with n to predict the electronic heat capacity: only the small fraction ∼T/TF\sim T/T_F of electrons near the Fermi surface participates, so CV∝TC_V \propto T — far from the classical 3kB/23k_B/2 per particle.

Simulation

Experiment history

In 1900 Paul Drude modeled conduction electrons as a classical gas; it explained the Wiedemann–Franz law but failed on electronic heat capacity — classical statistics gives every particle 3kB/23k_B/2, contrary to experiment. After Fermi and Dirac established the new statistics (1926), Arnold Sommerfeld applied it to metal electrons in 1928: only particles within ∼kBT\sim k_BT of the Fermi surface can be excited, naturally giving CV∝TC_V \propto T and the temperature-independent Pauli susceptibility. With EFE_F of a few eV, the « Fermi temperature » TF∼104T_F \sim 10^4–10510^5 K, so a metal at room temperature is still a degenerate gas — exactly the step distribution the simulation shows.

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